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In this work, a simple and rapid method to selectively sort semiconducting-SWCNTs (sc-SWCNTs) with large diameters using regioregular poly(3-dodecylthiophene) (rr-P3DDT) is presented. The absorption spectra and Raman spectra demonstrated that metallic species of arc discharge SWCNTs were effectively removed after interaction with rr-P3DDT in toluene with the aid of sonication and centrifugation. The sorted sc-SWCNT inks have been directly used to fabricate thin film transistors (TFTs) by dip-coating, drop-casting and inkjet printing. TFTs with an effective mobility of ∼34 cm<sup>2</sup> V<sup>-1</sup> s<sup>-1</sup> and on-off ratios of ∼10<sup>7</sup> have been achieved by dip coating and drop casting the ink on SiO<inf>2</inf>/Si substrates with pre-patterned interdigitated gold electrode arrays. The printed devices also showed excellent electrical properties with a mobility of up to 6.6 cm<sup>2</sup> V<sup>-1</sup> s<sup>-1</sup> and on-off ratios of up to 10 <sup>5</sup>. Printed inverters based on the TFTs have been constructed on glass substrates, showing a maximum voltage gain of 112 at a V<inf>dd</inf> of -5 V. This work paves the way for making printable logic circuits for real applications. © 2013 The Royal Society of Chemistry.

Original publication




Journal article



Publication Date





4156 - 4161