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Photofragmentation volammetry is used to demonstrate directly the primary loss of P(Ar)3 from [(η5-C5H 5)Fe(CO)(PAr3)=C(NHMe)Me] + BF4- (Ar = phenyl 1 and p-toly 2) on irradiation with visible light. In contrast, no loss of carbon monoxide is observed.

Type

Journal article

Journal

Journal of the Chemical Society, Perkin Transactions 2

Publication Date

01/12/1993

Pages

1005 - 1007