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Alkoxy carbene complexes incorporating the iron chiral auxiliary [(η 5 -C 5 H 5 )Fe(CO)(PPh 3 )] were prepared in good yields from either the corresponding acyl complexes or methoxymethyl complex of the auxiliary. A range of nucleophilic addition reactions to these alkoxy carbene complexes showed moderate to high diastereoselectivities and the reactive conformations of the carbene complexes under these conditions are discussed. © 2013 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.

Original publication

DOI

10.1039/c3nj00518f

Type

Journal article

Journal

New Journal of Chemistry

Publication Date

01/11/2013

Volume

37

Pages

3406 - 3410