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The antifungal antibiotic (-)-(1R,2S)-2-aminocyclopentane-1-carboxylic acid (cispentacin)8 and its cyclohexane homologue 14 have been prepared utilizing the highly stereoselective conjugate addition of homochiral lithium N-benzyl-N-α-methylbenzylamide 5. The corresponding trans-β-amino acids 10 and 16 were also prepared via the selective epimerization of the cis-β-amino ester conjugate addition products. © 1994 by the Royal Society of Chemistry. All Rights Reserved.

Original publication

DOI

10.1039/P19940001411

Type

Journal article

Journal

Journal of the Chemical Society, Perkin Transactions 1

Publication Date

01/01/1994

Pages

1411 - 1415