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Alkylation studies on the enolate of N-methyl morpholinone 7 clearly reveal that the observed cis-selectivity is consistent with a chiral relay system operating to invert the stereochemical information of the auxiliary's C5 stereogenic centre.

Original publication

DOI

10.1016/S0957-4166(98)00095-0

Type

Journal article

Journal

Tetrahedron Asymmetry

Publication Date

08/05/1998

Volume

9

Pages

1483 - 1487