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Chiral hydroxylamine chromium tricarbonyl complexes may be prepared in satisfactory to reasonable yieldvia nucleophilic aromatic substitution of the anion derived from N,O-substituted hydroxylamines and (η6-fluorobenzene) chromium tricarbonyl. The enantiomerically pure complex (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]- benzene} chromium tricarbonyl 6a was characterised by X-ray crystallography.


Journal article


Journal of the Chemical Society. Perkin Transactions 1

Publication Date



2850 - 2855