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He rearrangement of a range of N-benzyl-O-allylhydroxylamines to the corresponding N-allylhydroxylamines upon treatment with n-BuLi in THF, followed by reduction to the corresponding N-allylamines, is described. Mechanistic studies of the transformation are consistent with an intramolecular [2,3] sigmatropic rearrangement. © 2002 The Royal Society of Chemistry.

Original publication

DOI

10.1039/b205323n

Type

Journal article

Journal

Journal of the Chemical Society. Perkin Transactions 1

Publication Date

31/05/2002

Volume

2

Pages

1757 - 1765