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The synthesis and utility of the 3,3-dimethyl-5-substituted-2-pyrrolidinone 'Quat' chiral auxiliary in stereoselective enolate reactions of attached N-acyl side chains combined with the mild and non-racemising conditions required for the ultimate removal of the chiral side chain is described. © 2002 Elsevier Science Ltd. All rights reserved.

Original publication

DOI

10.1016/S0957-4166(02)00166-0

Type

Journal article

Journal

Tetrahedron Asymmetry

Publication Date

19/04/2002

Volume

13

Pages

647 - 658