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Stereoselective alkylation of (R)-[(η5-C5H5)Fe(CO)(PPh3)COCH2CH3] with bromomethyl-t-butyl sulphide, followed by oxidative decomplexation in the presence of L-proline t-butyl ester gave, after deprotection, (-)-Captopril enantiomerically and diastereomerically pure in an overall yield of 59%. © 1987.

Original publication

DOI

10.1016/S0040-4039(00)96782-0

Type

Journal article

Journal

Tetrahedron Letters

Publication Date

01/01/1987

Volume

28

Pages

5563 - 5564