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Nucleophilic addition reactions to the cations [(η5-C5H5)Fe(COXPPh3)(=CROMe)]+ (R = H, Et) are highly stereoselective. The product diastereoisomers [(η5-C5H5)Fe(COXPPh3XCHEtOMe)] undergo epimerization in methanol prior to formation of (E) [(η5-C5H5)Fe(CO)-(PPh3XCH=CHMe)]. © 1984, American Chemical Society. All rights reserved.

Original publication

DOI

10.1021/om00089a033

Type

Journal article

Journal

Organometallics

Publication Date

01/01/1984

Volume

3

Pages

1764 - 1765