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A novel [2,3]-sigmatropic rearrangement whereby N-benzyl-O-allylhydroxylamines undergo transformation to the corresponding N-allylhydroxylamines, which can subsequently be reduced to the corresponding allylamines, is described and evidence for the intramolecular nature of this process presented.

Original publication

DOI

10.1039/a806200e

Type

Journal article

Journal

Chemical Communications

Publication Date

21/10/1998

Pages

2235 - 2236