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A stereoselective two-carbon homologation protocol has been developed and applied to the asymmetric synthesis of the hexose monosaccharides D-galactose, D-fucose, D-idose, D-6-deoxyidose, D-talose and D-6-deoxytalose.

Original publication

DOI

10.1039/b415943h

Type

Journal article

Journal

Org Biomol Chem

Publication Date

21/01/2005

Volume

3

Pages

348 - 359

Keywords

Aldehydes, Glycolates, Hexoses, Molecular Conformation, Monosaccharides, Stereoisomerism